| Dinamo Zagreb | 0 – 2 | Paris S.G. |
| FC Porto | 3 – 2 | Dynamo Kyiv |
| Arsenal | 0 – 2 | Schalke |
| Montpellier | 1 – 2 | Olympiakos Piraeus |
| Zenit St. Petersburg | 1 – 0 | Anderlecht |
| Malaga | 1 – 0 | AC Milan |
| Ajax Amsterdam | 3 – 1 | Manchester C. |
| Borussia Dortmund | 2 – 1 | Real Madrid |
Hasil Liga Champions 24 Oktober 2012
